Couple things for OP:
Are you positive start/stop is not functioning due to the battery charge? The SS strategy seems pretty complicated for it to work and may not be battery related at all and is just normal operation. If you aren't getting deep sleep mode or other issues it's probably fine. I'm pretty sure the BMS is set to not exceed 80% state of charge anyway. Tough making sense of any of the voltage readings given how complex the system is.
Knock on wood I haven't had battery issues on my early 2021. Not even a deep sleep mode notification. Completely anecdotal, some of my modules were updated at an early service and I have had zero issues with OTA updates over the last 2+ years. My truck is also parked far underground in a concrete structure away from my key fobs.
Seems like some battery problems are related to module issues (not sleeping because key fob is too close, some self test/boot loop, who knows - some guy even had a video of his fuel pump not turning off that would drain the battery after a couple hours). Or the truck getting stuck in some voltage sucking OTA update glitch. There is also a TSB that may apply related to the A/C system causing a battery drain.